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It can be done but I would always recommend using the correct paint thinners. It is undoubtedly more expensive but it is designed specifically for the paint being thinned and, as such, evaporates at the same rate as the paint. This is important particularly when spraying gloss finishes.
If finish is not too important such as matt surfaces on a military vehicle you could probably get away with it but if you are particularly concerned about the finish I would use the corrrect thinners.
As for brush cleaning, once again the right stuff is a better solvent but you should be OK with white spirit, unless you want the brush to be spotles for a high gloss finish.
i personally use white spirits to thin revell enamels. it works fine but if i must say you do need to use quite a bit more than you would think and spray at a considerably higher pressure. but the finish is fine even for a high gloss one.
not sure about other brands though such has humbrol, older revell...etc
Now this last lot is the stuff I use all the time, you can buy this stuff at the local grocers store, if you just mix the enamel with this mineral turpentine 50 / 50, give it a shake, mix, whatever. Then start spraying the gloss enamel and when you reckon you have a good colour coat on the model, empty the colour out of the spray jar, fill it up with neat, plain mineral turps and while the paint is still wet, start spraying on the plain turps, only giving it light dusting coats with this straight turps, one or two coats is required, then put the model under cover ( cardboard box ) to stop any dust from settling on it.
What this does is actually thin down the top of the wet colour paint and draw it out nice and smooth.
You get an excellent gloss finish by doing this, if you just spray on the colour and leave it, you can and will get a faint orange peel look to the finish coat, spray on the plain turps and bingo, mirror type finish.
Give it a go and see what results you can get, you can use whatever you thinned the paint with, as it will then be compatible with the paint.
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