Interesting not really sure what toxic means (my referral to toxic is a Laurie definition). But thought it related to the harm that it can do to living objects by using certain substances. The toxicity can be harmful depending on the exposure to the substances. Humans and animals vary in their vulnerability to a toxic substance. That is some may not be vulnerable at all some may be at the slightest whiff or touch of a toxic substance. Think all that is reasonably correct.
First I did not choose to use acrylics because I thought they would or would not produce a better finish than Enamels or were easier to use.
I chose acrylics as for me enamel paint was harmful. It gave me a thundering headache even with a fan to remove it the stuff. The thinners white spirit also produced a nettle rash (should have known as petrol does the same) not within secs but say after a night of spraying and cleaning. Whether this in scientific terms is toxic I have no idea.
I also suffer from a dratted skin disease called Psoriasis. Use of thinners aggravated this complaint making the skin red raw at times. In fact for all these reasons if it had not been for acrylics I would have had to pack it all in.
I then turned to acrylics, water based, and have not had any of the above problems since. So for me enamels are toxic (by my definition) for others not so. I suppose there is the possibility they affect some without them realising but then you could say the same about Vallejo thinner or probably more so the Vallejo airbrush Cleaner which is more potent than the thinner. Although I have not heard of any complaints in this direction.
Not tried the Tamiya solvent based acrylics so I cannot tell if that would have a harmful effect to me.
So if you are allergic in any way then I would be careful as from my understanding and experience allergic reactions grow in intensity with the use and carry on, hopefully with an end insight, for a time after the substance is no longer used.
Leaving the above aside I just found that using enamel thinners permeated throughout the house with this awfull smell.
I would say to any one get some enamel and some acrylic paint and try both (not at the same time). It is the only way that you are going to find if you are allergic to one or the other. Also to find the capabilities the ease of use and which finish you like best. In my opinion, from what I have seen, superb models have been produced here in both acrylic and enamels.
Bit of irony. I swear by acrylics for painting due to all the above. However if I walk through M and S I have an allergic reaction to all the acrylic clothing in the place.
Laurie